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Alkylation of naphthalene and toluene by ethylene in naphthalene/alkali metal systems in THF

✍ Scribed by S. Rummel; M. A. Ilatovskaya; H. Langguth; V. B. Shur

Publisher
Springer
Year
1999
Tongue
English
Weight
163 KB
Volume
48
Category
Article
ISSN
1573-9171

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Polymerization of ethylene oxide by alka
Polymerization of ethylene oxide by alkali metal-naphthalene complexes in tetrahydrofuran
✍ K.S. Kazanskii; A.A. Solovyanov; S.G. Entelis πŸ“‚ Article πŸ“… 1971 πŸ› Elsevier Science 🌐 English βš– 571 KB

The kinetics of ethylene oxide polymerization in THF, with Na, K and Cs-naphthalene complexes as initiators, have been studied in detail. Polymerization is first order with respect to monomer without chain termination or transfer. The complicated dependence of the polymerization rate on active cent