As part of a programme involving X-ray crystallographic studies" of cis-and tpuns-fused hexopyranosides, we now report on the crystal structures of methyl 2-~-methyl-~-D-glucop~anoside\* (11, which was obtained by debe~lidenation of methyl 4,~-O-benzyIidene-2-O-methyI-3-O-~-tolylsulfonyl-~-~-glucopy
✦ LIBER ✦
Alkylation of methyl 4,6-O-benzylidene-α-D-galactopyranoside
✍ Scribed by V. I. Grishkovets; V. Ya. Chirva
- Book ID
- 112377896
- Publisher
- Springer
- Year
- 1982
- Tongue
- English
- Weight
- 386 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0009-3130
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The crystal structures of methyl 6-O-n-octanoyl-a-o-galactopyranoside (1) and methyl 6-O-ndecanoyl-a-D-galactopyranoside (2) were investigated by X-ray analysis. Anhydrous crystals obtained from methanol solution by slow evaporation are monoclinic, and the space group is P21 with Z = 2. The cell dim