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Alkylation and decarboxylation of ethyl 2-fluoro-3-oxobutanoate as a route to functionalised α-fluoro-ketones

✍ Scribed by J. Hutchinson; Graham Sandford; Julian F.S. Vaughan

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 449 KB
Volume: 54
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(98)83023-8

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✦ Synopsis

Alkylation and decarboxylation of a-fluoro-[3-ketoesters such as ethyl 2-fluoro-3oxobutanoate offers a versatile route to a range of fluoro-ketoalkenes, demonstrating the synthetic utility of using ~-fluoro-[~-ketoesters as synthons for the preparation of synthetically more sophisticated selectively fluorinated systems.

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