Stereoselective aldol condensation react
β
Lanny S. Liebeskind; Mark E. Welker
π
Article
π
1984
π
Elsevier Science
π
French
β 237 KB
By proper choice of counterion, the enolate of n5-CpFe(CO)(PPh3)COCH3 will react with aldehydes to form the aldol products with high stereoselectivity. Chiral iron acyls, n5-CpFe(CO)(PPh3)COCH2R, can be deprotonated by strong base to the corresponding enolates that then react with organic electrophi