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Alkyl Transition Metal Compounds IX. Synthesis and structure of [(Me3SiCH2)2Cr(bipy)2] I

✍ Scribed by J. J. Daly; F. Sanz; R. P. A. Sneeden; H. H. Zeiss


Publisher
John Wiley and Sons
Year
1973
Tongue
German
Weight
233 KB
Volume
56
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

Bis(trimethylsilylmethyyl)‐bis‐(2,2′‐bipyridyl)chromium(III) iodide has been synthesized and its structure determined; the Cr‐C(sp^3^) bond length is 2.107(9) Γ….


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Synthesis and Crystal Structure of Me3NH
✍ Roland Hehl; Gerhard Thiele πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 German βš– 172 KB πŸ‘ 1 views

Attempts to build up polyanionic networks on the basis of thiocyanatometallates of Cu I and Ag I led to the synthesis of three new tris(thiocyanato)dimetallates(I) A[M 2 (SCN) 3 ] with M = Cu, Ag and A = Me 3 NH and A = [Me 2 CNMe 2 ]. The crystal structures show distorted tetrahedral [M(SCN) 3 (NCS