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Alkyl group substituent effects in the adamantane system. Fluorine-19 chemical shifts

โœ Scribed by Wahl, George H.; Peterson, Max R.

Book ID
126305071
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
251 KB
Volume
92
Category
Article
ISSN
0002-7863

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## Abstract The effect of introduction of fluorinated groups (CH~2~F, CHF~2~, CF~3~, C~2~F~5~, OCF~3~, SCF~3~) on the ^13^C NMR chemical shifts in cyclohexanes is examined. The two main effects are caused by location at the ฮฑ and ฮณ carbon positions. Comparison of the various data allowed the calcul