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Alkyl Exchange Reactions of Organocobalt Porphyrins. A Bimolecular Homolytic Substitution Reaction

✍ Scribed by Stolzenberg, Alan M.; Cao, Yang

Book ID
119952292
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
133 KB
Volume
123
Category
Article
ISSN
0002-7863

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## Abstract Cyano‐substituted methyl radicals (cyanomethyl–hand 2‐cyano‐2‐propyl radicals) and __syn__‐and __anti__‐1‐cyano‐allyl radicals were generated, and their recombination kinetics in solution were investigated between −50 and +50°C by time‐resolved electron‐spin‐resonance spectroscopy. The