Alkyl- and Arylthiolation of Aryl Halides Catalyzed by Fluorinated Bis-Imino-Nickel NNN Pincer Complexes [NiCl2{C5H3N-2,6- (CHNArf)2}].

Alkyl- and Arylthiolation of Aryl Halide

Alkyl- and Arylthiolation of Aryl Halides Catalyzed by Fluorinated Bis-Imino-Nickel NNN Pincer Complexes [NiCl2{C5H3N-2,6-(CHNArf)2}]

✍ Oscar Baldovino-Pantaleón; Simón Hernández-Ortega; David Morales-Morales 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 134 KB

## Abstract The synthesis of bis‐imino nickel(II) NNN pincer complexes of the type [NiCl~2~{C~5~H~3~N‐2,6‐(CHNAr~__f__~)~2~}]; Ar~__f__~=C~6~H~3~‐2,3‐F~2~ (1), C~6~H~3~‐2,5‐F~2~ (2), C~6~H~3~‐3,4‐F~2~ (3), C~6~H~3~‐3,5‐F~2~ (4), C~6~H~2~‐2,3,4‐F~3~ (5), C~6~H~2~‐2,3,6‐F~3~ (6), C~6~H~2~‐2,4,5‐F~3~