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Alkyl- and Aryl-Substituted Corroles. 5. Synthesis, Physicochemical Properties, and X-ray Structural Characterization of Copper Biscorroles and Porphyrin−Corrole Dyads

✍ Scribed by Guilard, Roger; Gros, Claude P.; Barbe, Jean-Michel; Espinosa, Enrique; Jérôme, François; Tabard, Alain; Latour, Jean-Marc; Shao, Jianguo; Ou, Zhongping; Kadish, Karl M.

Book ID: 124163804
Publisher: American Chemical Society
Year: 2004
Tongue: English
Weight: 345 KB
Volume: 43
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic049651c

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## Abstract The reaction of the new, bis(bidentate), potentially dinucleating ligand 4‐isobutyl‐3,5‐di(2‐pyridyl)‐4__H__‐1,2,4‐triazole (ibdpt) with M(ClO~4~)~2~·6H~2~O (M = Co^II^, Ni^II^ or Cu^II^) in a1:1 molar ratio in MeCN affords the dinuclear complexes [Co^II^~2~(ibdpt)~2~(MeCN)~2~(H~2~O)~2~