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Alkenes from Alcohols by Tandem Hydrogen Transfer and Condensation

✍ Scribed by Michael I. Hall; Simon J. Pridmore; Jonathan M. J. Williams

Book ID
101421315
Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
174 KB
Volume
350
Category
Article
ISSN
1615-4150

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📜 SIMILAR VOLUMES

From allylic alcohols to aldols via a no
From allylic alcohols to aldols via a novel, tandem isomerization–condensation catalyzed by Fe(CO)5
✍ Christophe Crévisy; Marina Wietrich; Virginie Le Boulaire; Ramalinga Uma; René G 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 85 KB

Allylic alcohols react with aldehydes, in the presence of catalytic amounts of Fe(CO) 5 and under irradiation, to give mainly aldol products. A small amount of ketone resulting from the classical isomerization process is also isolated. This new aldol-type reaction is a complete atom economy process