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Alkane dehydrogenation catalyzed by rhodium(I) phosphine complexes: observation of the stoichiometric alkane-to-rhodium hydrogen-transfer step

✍ Scribed by Shih, Kuo Chen; Goldman, Alan S.


Book ID
125950966
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
331 KB
Volume
12
Category
Article
ISSN
0276-7333

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Chelate complexes of the type [ Rh( q2-0,Z) (PR,),] (Z = CCH,, CCF3, CtBu, S( 0) -p-C&I&H,; PR, = PiPr,, PPhiPr,, PPh,iPr) catalyze the hydrogenation of phenylacetylene in toluene solution at 60Β°C. Selectivities close to 100% are achieved for the hydrogenation of the alkyne to the alkene in the pre