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Alkane activation by homogeneous palladium complexes

✍ Scribed by James K Beattie; Anthony F Masters; Meredith L Sparkes

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 264 KB
Volume: 5
Category: Article
ISSN: 0268-2605
DOI: 10.1002/aoc.590050611

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✦ Synopsis

The conversion of adamantane exclusively to 1adamantyl trifluoroacetate in a refluxing trifluoroacetic acid solution of palladium acetate at 1 atm of air or nitrogen was confirmed. The conversion can be made quantitative. The 1-adamantyl trifluoroacetate was hydrolysed to yield 1adamantanol in 90 '/o isolated yield. The adamantane functionalization is accompanied by concomitant formation of a palladium mirror.

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