𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Alkaloid total synthesis by intramolecular imino Diels-Alder cycloadditions

✍ Scribed by Weinreb, Steven M.


Book ID
121505529
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
677 KB
Volume
18
Category
Article
ISSN
0001-4842

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Total Synthesis of (Β±)-Lysergic Acid by
✍ Wolfgang Oppolzer; Eric Francotte; Kurt BΓ€ttig πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 German βš– 252 KB

## Abstract (Β±)‐Lysergic acid (**1**) has been synthesized from 4‐hydroxymethyl‐1‐tosylindole (**2**) by a sequence of 9 steps. The crucial thermolysis **9** β†’ **10** involves the __in situ__‐generation of the transient diene III which undergoes an intramolecular cycloaddition to a C, N‐double bond

Imino Diels-Alder cycloadditions: An app
✍ Michele Maggini; Maurizio Prato; Gianfranco Scorrano πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 242 KB

A formal synthesis of (f)-aristeromycin starting from the imino Diels-Alder cycloadduct 38 has been achieved with high overall yield. A novel method for the in sifu preparation of N-sulfonylimines is reported.