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Alkali—SCl2 chemiluminescence: Vibrational population inversion in the B state of S2

✍ Scribed by J.J. Wright; L.C. Balling

Book ID
103028724
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
304 KB
Volume
108
Category
Article
ISSN
0009-2614

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✦ Synopsis

Sz(B -X) chelnilurninescence, primarily from V' = 0 and 1, has been observed in alkali atom-SC12 reactions.

The addition of tie or Ar buffer gas to the reaction chamber alters the reaction dynamics, and at certain buffer gas pressures the S2 emission originates esclusively from the U' = 6-9 vibrational levels of the Bc3Z;) state.

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