Alkaline Oxygen Oxidation of Dioxane Lignin and Creosol in Aqueous Ethanol
✍ Scribed by Hagström-näsi, Christine; Sjöström, Eero
- Book ID
- 120605462
- Publisher
- Taylor and Francis Group
- Year
- 1988
- Tongue
- English
- Weight
- 340 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0277-3813
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📜 SIMILAR VOLUMES
The kinetics of oxidation of 1,4-Dioxane (Dio) by Diperiodatonickelate (IV) (DPN) in aqueous alkaline medium at a constant ionic strength of 1.5 mol dm Ϫ3 was studied spectrophotometrically. The reaction shows first-order kinetics in [DPN] and less than unit order dependence each in [Dio] and [OH Ϫ
Basic reactions governing the degradation of lignin in oxidation with molecular oxygen are discussed emphasizing the radical (homoly~ic) or one-electron transfer-oxidations in the initial phase. The eriticM oxidation potentials (COP) according to Fieser were found to represent a useful measure for t