The hydrolysis of some p-substituted triphenylsilanes in the presence of tetrabutylammonium hydroxide has been investigated in various water-acetonitrile media with the aim of comparing the results with those already published for triphenylsilane. It appears that the initial rate is first order with
โฆ LIBER โฆ
Alkaline Hydrolysis of Triphenylsilane in Acetonitrile. A Comment on the Structure of the Transition State
โ Scribed by J.-J. Tondeur; A. Borghese; G. Vandendunghen
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 94 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0037-9646
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The group dependence, i.e., the variation with the number of d valence electrons, of vacancy parameters in transition metals with the body-centered cubic (bcc) structure is investigated via a combination of electronic structure calculation techniques. A semiempirical tight-binding d-band approach is