In our last pa&u (I) it ras reported that in the olkaline'hydrolysis of substituted ethyl bensoates the change of the solvent from' 85 %(rt.) aqueous ethanol to 3 %(rt.) aqueous ethanol caused 5C times increase in the rate of the unsubstituted compound and decrease to a half in the Bammett p value,
Alkaline hydrolysis of dicarboxylic esters in aqueous dimethyl sulfoxide
β Scribed by N. Venkatasubramanian; G.Venkoba Rao
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- French
- Weight
- 295 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Subsequent to the review artlole of Pmker 1) wherein he had pointed out the remarkable rate enha&& ability of dipolu a$rotio aolventr euoh am dimethpl aulfoxide on S# reaotlona in~olrl.ng anions, amer of paper6 hare appeared on the alkaline hydrolysis of monoeater in DlBO -water mixtures "!
π SIMILAR VOLUMES
The maximum hydration of dimethyl sulfoxide (DMSO) in aqueous solution at 25" was investigated by the deviation of experimental values of fluidity, dielectric constant, refractive index, density, and molar refraction from values calculated by linear interpolation between the values of the two pure l