Alkaline hydrolysis of cinnamaldehyde to benzaldehyde in the presence of β-cyclodextrin
✍ Scribed by Hongyan Chen; Hongbing Ji
- Publisher
- American Institute of Chemical Engineers
- Year
- 2009
- Tongue
- English
- Weight
- 368 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0001-1541
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The radical polymerization of N-tert-butyl-N-allylacrylamide (t-BAA) was carried out in a dimethyl sulfoxide/H 2 O mixture in the presence of -cyclodextrin (-CD). The polymerization proceeded with the complete cyclization of the t-BAA unit and yielded optically active poly(t-BAA). The IR spectrum
The opening of ortho-substituted phenyl oxiranes by borohydrides is described both in aqueous and solid phases. Some remarkable differences in the regioselectivity and inversion of enantioselectivity of oxirane ring-opening are reported. The results obtained are compared with previous studies and ha