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Alkaline Hydrogen Peroxide Oxidation of a Steroidal α,β-Unsaturated Ketone. A Baeyer—Villiger Product 1

✍ Scribed by Levine, Seymour D.


Book ID
121324832
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
527 KB
Volume
31
Category
Article
ISSN
0022-3263

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Highly efficient epoxidation of α,β-unsa
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The base hydrotalcite, prepared from MgO and Al 2 O 3 , acted as a highly efficient catalyst for the epoxidation of a,b-unsaturated ketones using aqueous hydrogen peroxide as an oxidant. This heterogeneous epoxidation has the advantages of a high efficiency of H 2 O 2 utilization without organic sol