Alkaline cleavage of 1- and 4-cyclooctenecarboxylic acids to azelaic acid
β Scribed by L. I. Zakharkin; G. G. Zhigareva
- Book ID
- 112420133
- Publisher
- Springer
- Year
- 1965
- Tongue
- English
- Weight
- 159 KB
- Volume
- 14
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
Treatment of 3-aroyloxy-and 2-(aroyloxymethyl)tetrahydrofurans with TiCI 4 results in cleavage of the heterocyclic ring with intervention by the appropriately situated ester group to form intermediates which, on work-up and hydrolysis, furnish 1,4-diols. The Lewis acid mediated cleavage of tetrahyd
Diene and 1,4-enyne containing chains are exhibited in a wide variety of natural structures including fatty acids, insect pheremones and abnormal acyclic terpenes. Recently , the synthesis of such unsaturated systems has elicted considerable attention. ' We wish to disclose a new route to these unsa