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Alkaline and acidic hydrolysis of the β-lactam ring

✍ Scribed by J. Frau; M. Coll; J. Donoso; F. Muñoz; B. Vilanova; F. García-Blanco

Book ID: 112083099
Publisher: John Wiley and Sons
Year: 1997
Weight: 168 KB
Volume: 2
Category: Article
ISSN: 1082-4928
DOI: 10.1002/ejtc.34

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We used semi-empirical and ab initio calculations to investigate the nucleophilic attack of the OHion on the 8-lactam carbonyl group. Both allowed us to detect reaction intermediates pertaining to proton-transfer reactions rather than the studied reaction. We also used the PM3 semi-empirical method