Alkali Metal Complexes of the Pendant Arm Macrocyclic Ligand 1,4,7,10-Tetrakis(2-methoxyethyl)-1,4,7,10-tetraazacyclododecane. An Equilibrium and Inter- and Intramolecular Exchange Study
✍ Scribed by Stephens, Ashley K. W.; Dhillon, Ramesh S.; Madbak, Samer E.; Whitbread, Sonya L.; Lincoln, Stephen F.
- Book ID
- 127112662
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 341 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0020-1669
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## Abstract The ligand H~5~dotasa (=(__αRS__)‐__α__‐(carboxymethyl)‐1,4,7,10‐tetraazacyclododecane‐1,4,7,10‐tetraacetic acid) is a H~4~dota‐like macrocyclic ligand with a carboxymethyl CH~2~COOH substituent at the C(__α__) atom of one of the four acetate pendant arms of H~4~dota (=1,4,7,10‐tetraaza
## Abstract NMR, potentiometric, and UV/VIS measurements were run to study the protonation and the In^3+^ and Cu^2+^ stability constants of 1,4,7,10‐tetraazacyclododecane‐1,4,7‐triacetic acid (do3a, L). The protonation of do3a follows the typical scheme with two high and several low log __K__~H~ va