Alkali (alkaline-earth) metal, aluminum, and titanium complex orthophosphates: Synthesis and characterization
✍ Scribed by T. S. Sysoeva; E. A. Asabina; V. I. Pet’kov; V. S. Kurazhkovskaya
- Book ID
- 110182283
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2009
- Tongue
- English
- Weight
- 467 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0036-0236
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## Abstract Compound [(dph‐BIAN)Mg(THF)]~2~ (**2**) was prepared by reacting magnesium metal with 1,2‐bis[(2‐biphenyl)imino]acenaphthene (dph‐BIAN) in THF, followed by crystallization from toluene. Reaction of CaI~2~ with (dpp‐BIAN)Li~2~ in toluene afforded [(dpp‐BIAN)Li]~2~Ca (**3**) (dpp‐BIAN = 1
## Abstract Compound [(dph‐BIAN)Mg(THF)]~2~(**2**) was prepared by reacting magnesium metal with 1,2‐ bis[(2‐biphenyl)imino]acenaphthene (dph‐BIAN) in THF, followed by crystallization from toluene. Reac‐ tion of CaI~2~ with (dpp‐BIAN)Li~2~ in toluene afforded [(dpp‐BIAN)Li]~2~Ca (**3**) (dpp‐BIAN =