## Abstract The cleavage of different photoinitiators (PIs) of polymerization is investigated by the ESR spin trapping using two different spin traps (STs): 5,5β²βdimethylβ1βpyrroline __N__βoxide (DMPO) and phenyl __N__β__tert__βbutyl nitrone (PBN). The hyperfine splitting constants for the differen
Aliphatic Semidiones; Application of Electron Spin Resonance to Problems of Conformation
β Scribed by G. A. Russell
- Publisher
- John Wiley and Sons
- Year
- 1966
- Tongue
- English
- Weight
- 120 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
β¦ Synopsis
Pyrolysis of cross-linked polymers, e.g. furan resins, leads to impermeable carbons with He densities of 1.55 g/cm3. Smallangle scattering showed the presence of uniform pores of 20-30 A diameter.
Cellulose can be thermally degraded to flexible graphite fibers and it was shown by wide-and small-angle X-ray diffraction that the fibrillar structure of the cellulose is retained in the carbon residue. If flexible products are to be obtained it is necessary to avoid formation of tarry byproducts by instant removal of pyrolysis gases.
π SIMILAR VOLUMES
An electron spin aligned with a static magnetic field changes its orientation when subjected to a time-varying magnetic field which is directed perpendicular to the static magnetic field. This well-known phenomenon is readily calculated when the time-varying magnetic field is circularly polarized; h