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Aliphatic polyketone obtained by cationic polymerization of ethylketene

✍ Scribed by Hayki, Najib; Desilles, Nicolas; Burel, Fabrice


Book ID
120390212
Publisher
The Royal Society of Chemistry
Year
2011
Tongue
English
Weight
215 KB
Volume
2
Category
Article
ISSN
1759-9954

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✍ Najib Hayki; Nicolas Desilles; Fabrice Burel πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 297 KB

## Abstract Aldoketenes are well known to undergo fast dimerization and trimerization even at low temperatures but have never been polymerized so far. For the first time, ethylketene, synthesized following the Staudinger procedure modified by McCarney, was polymerized anionically in THF with variou

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## SYNOPSIS endo-Dicyclopentadiene (DCPD) was polymerized by various cationic initiating systems in different solvents. IR and 'H NMR results show that four types of structural units are formed due to the corresponding addition modes: the addition on the norhornenic (NB) double bond generates unit