Algebraic approach to molecular rotation-vibration spectra. I. Diatomic molecules
✍ Scribed by Iachello, F.
- Book ID
- 120070358
- Publisher
- American Institute of Physics
- Year
- 1982
- Tongue
- English
- Weight
- 978 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.444228
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📜 SIMILAR VOLUMES
The rotation-vibration spectra of diatomic molecules are discussed with the aid of the SO ( 2.1) dynamic group. The eigenvector of the compact generator is explicitly obtained by realizing the generators in the four-dimensional polar coordinates. A special representation of the radial part of the ge
A new method leading to exact analytic solutions of the ro~tion-vibmtional Schrijdinger equation for diatomic molecules is proposed. The eigenvalues obtained are applied in the evaluation of molecular constants and reproduction of rovibrational spectra of '\*CJ2S, HF, and the van der Waals molecule