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AlEt3–metal soap catalysts for the polymerization of epoxides

✍ Scribed by Takahashi, Akio ;Gaylord, Norman G.

Publisher
Wiley (John Wiley & Sons)
Year
1966
Tongue
English
Weight
254 KB
Volume
4
Category
Article
ISSN
0449-296X

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The kinetics of I-octene polymerization by the catalyst systems VO(acac),-AlEt, (I) and VO(acac),-AlEt,Br (II) was investigated. A linear dependence of the rate of polymerization on the monomer and catalyst concentrations as well as the overall activation energy of 44.5 kJ/mol for both the catalyst