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Alcohol modifiers in MEKC with SDS as surfactant. Study on the influence of the alcohol chain length (C1C12)

✍ Scribed by Van Hove, Erik ;Szücs, Roman ;Sandra, Pat


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
388 KB
Volume
19
Category
Article
ISSN
0935-6304

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✦ Synopsis


Abstract

The influence of alcohol modifiers with different chain length on the migration time window in micellar electrokinetic chromatography (MEKC) has been studied. Highly polar alcohols like methanol and 1‐propanol are typical aqueous phase modifiers. Higher alcohols like 1‐butanol, 1‐pentanol and 1‐hexanol influence the micellar structure and are considered as micellar phase modifiers. The effect of long chain alcohols is small because of their low applicable concentrations.