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[Al(Al3R3)2] (R=N(SiMe2Ph)2): Prototyp eines metalloiden Al-Clusters oder ein sandwichstabilisiertes Al-Atom?

✍ Scribed by Ping Yang; Ralf Köppe; Taike Duan; Jens Hartig; Gunar Hadiprono; Bernd Pilawa; Ilka Keilhauer; Hansgeorg Schnöckel

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
242 KB
Volume
119
Category
Article
ISSN
0044-8249

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[ScCl2{N(SiMe3)2}(THF)2] als Vorläufer f
[ScCl2{N(SiMe3)2}(THF)2] als Vorläufer für die Synthese von Scandiumnitrid
✍ Marc Karl; Gerd Seybert; Werner Massa; Kurt Dehnicke 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 72 KB

ScCl 2 {N(SiMe 3 ) 2 }(THF) 2 ] ± a Precursor for the Synthesis of Scandium Nitride Abstract. [ScCl 2 {N(SiMe 3 ) 2 }(THF) 2 ] (1) has been prepared by the reaction of [ScCl 3 (THF) 3 ] with the trisamide Sc[N(SiMe 3 ) 2 ] 3 in tetrahydrofurane solution forming colourless moisture sensitive crystals