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Air-Stable Bifunctional Allylation Reagents for the Asymmetric Synthesis of Differentiated syn - and anti -1,3-Diols

✍ Scribed by Lee, Jae Seung; Kim, Dongeun; Kong, Suk Bin; Han, Hyunsoo


Book ID
120024562
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
326 KB
Volume
19
Category
Article
ISSN
0947-6539

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πŸ“œ SIMILAR VOLUMES


Synthesis of 4, 6-dialkyl-1,3-dioxins. V
✍ Raymond L Funk; Gary L Bolton πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 French βš– 271 KB

The title compounds 4 are prepared from 4-alkyldioxins 2 via a metalation, alkylation sequence. The dialkyl dioxins 4 are thermally labile (providing enones) and undergo highly stereoselective hydroboration or hydrogenation reactions to provide enti,anti-1,2,3-triols and syn-1,3-diols, respectively.