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Ag(I)-Catalyzed Regioselective Ring-Opening of N-Tosylaziridine and N-Tosylazetidine with S-, O-, and N-Nucleophiles and Tethered Dinucleophiles

✍ Scribed by Bera, Milan; Pratihar, Sanjay; Roy, Sujit


Book ID
111937763
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
853 KB
Volume
76
Category
Article
ISSN
0022-3263

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## Abstract Asymmetric ring‐opening reactions of __N__‐Boc‐azabenzonorbornadiene with __N__‐substituted piperazine nucleophiles in the presence of 5 mol% of [Rh(COD)Cl]~2~ and 10 mol% of chiral ligand, (__R__,__S__)‐PPF‐P‐__t__‐Bu~2~, gave the corresponding 1,2‐diamine product in moderate to excell