Aggregative activation and carbanion chemistry : complex base deprotonation and directed functionalisation of dithioacetals
✍ Scribed by Philippe Gros; Philippe Hansen; Paul Caubére
- Book ID
- 104207367
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 589 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Aggregative Activation in Heterocyclic Chemistry. Part 5. Lithiation of Pyridine and Quinoline with the Complex Base BuLi•Me 2 N(CH 2 ) 2 OLi (BuLi•LiDMAE). -In continuation of earlier results the title metalation and subsequent reaction with different electrophiles is investigated. In reactions wit
Benzyl dialkyl phosphates are deprotonated enantioselec-up to 50%. The pro-(S) hydrogen is removed by amides hatively by homochiral lithium amides of isopropyl( 1-phenyl-ving (S) configuration. Homochiral diethyl (S)-phenyl[D+ ethy1)amine or bis(1-phenylethy1)amine. The short-lived ben-methyl phosph