𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Aggregative activation and carbanion chemistry : complex base deprotonation and directed functionalisation of dithioacetals

✍ Scribed by Philippe Gros; Philippe Hansen; Paul Caubére


Book ID
104207367
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
589 KB
Volume
52
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


ChemInform Abstract: Aggregative Activat
✍ P. GROS; Y. FORT; P. CAUBERE 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 40 KB 👁 1 views

Aggregative Activation in Heterocyclic Chemistry. Part 5. Lithiation of Pyridine and Quinoline with the Complex Base BuLi•Me 2 N(CH 2 ) 2 OLi (BuLi•LiDMAE). -In continuation of earlier results the title metalation and subsequent reaction with different electrophiles is investigated. In reactions wit

Enantioselective Deprotonation of Benzyl
✍ Hamerschmidt, Friedrich ;Hanninger, Achim 📂 Article 📅 1995 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 829 KB

Benzyl dialkyl phosphates are deprotonated enantioselec-up to 50%. The pro-(S) hydrogen is removed by amides hatively by homochiral lithium amides of isopropyl( 1-phenyl-ving (S) configuration. Homochiral diethyl (S)-phenyl[D+ ethy1)amine or bis(1-phenylethy1)amine. The short-lived ben-methyl phosph