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Aggregation of some water-soluble derivatives of chitin in aqueous solutions: Role of the degree of acetylation and effect of hydrogen bond breaker

✍ Scribed by Olga E. Philippova; Evgeniya V. Korchagina; Evgeny V. Volkov; Valery A. Smirnov; Alexei R. Khokhlov; Marguerite Rinaudo


Book ID
113514807
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
816 KB
Volume
87
Category
Article
ISSN
0144-8617

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## Abstract A model of the specific acid‐catalyzed glycosidic bond formation in liquid water at ambient conditions is studied based on constrained Car–Parrinello ab initio molecular dynamics. Specifically the reaction of α‐D‐glucopyranose and methanol is found to proceed by a D~N~A~N~ mechanism. Th