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Agariblazeispirol C from the cultured mycelia of the fungus, Agaricus blazei, and the chemical conversion of blazeispirol A

โœ Scribed by Masao Hirotani; Miyuki Masuda; Aya Sukemori; Seiko Hirotani; Noriko Sato; Takafumi Yoshikawa

Book ID
108282809
Publisher
Elsevier Science
Year
2005
Tongue
French
Weight
293 KB
Volume
61
Category
Article
ISSN
0040-4020

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Blazeispirol A, an unprecedented skeleto
Blazeispirol A, an unprecedented skeleton from the cultured mycelia of the fungus Agaricus blazei
โœ Masao Hirotani; Seiko Hirotani; Hiroaki Takayanagi; Takafumi Yoshikawa ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 193 KB

Blazeispirol A, an unprecedented skeleton has been isolated from the cultured mycelia of Agaricus blazei(Agaricaceae). Its structure was elucidated to be the previously unknown spiro [4,10b-ethanonaphtho[l,2b]pyran-2,2'-furan] skeleton which was established by extensive 1D and 2D NMR spectral data a

Biosynthesis of blazeispirol A, an unpre
Biosynthesis of blazeispirol A, an unprecedented skeleton from the cultured mycelia of the fungus Agaricus blazei
โœ Masao Hirotani; Asami Kaneko; Yoshihisa Asada; Takafumi Yoshikawa ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 169 KB

The biosynthesis of blazeispirol A, an unprecedented skeleton, was investigated by feeding 13 C-labeled acetates, propionate and methionine, to the growing cultures of Agaricus blazei (Agaricaceae). 13 C NMR spectral analysis demonstrated the mevalonate origin of the spiroacetal moiety and the dihyd