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Ag3SnP7: A Polyphosphide with a Unique (P7) Chain and a Novel Ag3Sn Heterocluster

✍ Scribed by Mikhail M. Shatruk; Kirill A. Kovnir; Andrei V. Shevelkov; Boris A. Popovkin

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
110 KB
Volume
39
Category
Article
ISSN
0044-8249

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Mo(V) Phosphates with an Opened Framework: Li4βˆ’xA+x(MoO)3(PO4)3P2O7(A=Na, Ag, Cs, K), Li4βˆ’xBa2+x/2(MoO)3(PO4)3P2O7
✍ S. Ledain; A. Leclaire; M.M. Borel; M. Hervieu; J. Provost; B. Raveau πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 English βš– 514 KB

The exploration of Li+A+Mo+P+O systems has allowed several Mo(V) phosphates, Li 4؊x A x (MoO) 3 (PO 4 ) 3 P 2 O 7 (A ‫؍‬ Na, Ag, Cs, K) and Li 3 Ba 0.5 (MoO) 3 (PO 4 ) 3 P 2 O 7 , to be synthesized. Two types of closely related structures are evidenced depending on the nature and content of the A ca