AES and UPS studies of CO and CO2 adsorption on Mg and MgO
β Scribed by Yasuo Fukuda; Isamu Toyoshima
- Publisher
- Elsevier Science
- Year
- 1985
- Weight
- 44 KB
- Volume
- 158
- Category
- Article
- ISSN
- 0167-2584
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A Pt/TiO 2 sample has been studied by adsorption and co-adsorption of CO and NO. It has been found that platinum is present in different oxidation states on the surface of the activated sample. Pt 4+ ions are coordinatively saturated and form complexes neither with CO nor with NO. Pt 3+ ions form, a
The structure and binding energies are determined for M&CO,).+ and Sr(CO,),' for n= 1 and 2. We also consider Mg: and Mg#ZO: to compare the binding of CO1 to a single metal ion with the binding to a diatomic ion. The vertical excitation energies are computed for all species. The potential energy cur