Aerothermochemical studies of energetic liquid materials: 3. Approximate determination of some thermophysical and thermochemical properties of organic azides

✍ Scribed by A. Lee; C.K. Law; A. Makino

• Publisher: Elsevier Science
• Year: 1989
• Tongue: English
• Weight: 631 KB
• Volume: 78
• Category: Article
• ISSN: 0010-2180
• DOI: 10.1016/0010-2180(89)90016-3

✦ Synopsis

l)epartment of .*¢lechanicul Engineering, (.,'niver~ty ol ( 'tdifornia, l)m'i~', ('4 95616 l'hr.mgh either direct measurement or group additivily calculation, the densitms, normal b~filing points, latent heatof vaporization, limits of superheat, enthalpies of formation, combustion anti dccomposition, anti adiabatic, llatnt. temperatures have been approximately determined for the mono-and dl-substituted alkyl azides, which cxhd'ut significantly enhanced droplet gasification rates and microexploslon events. Slmdar determinations have al,,o been performed lot son'te alkyl halides, especially alkyl bromides; the similartt3 of their properties with those ol thv organic azides are noted. Implications o| the thermophysical and therm~u.'hemical properties determined hcrcm o~, the i:x~tential of the organic azides and halides as .let fuels and;or ict fuel additives arc discussed