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Aerobic oxidation of trivalent phosphorus and arsenic compounds in the presence of 3-methylbutanal and metal catalyst

✍ Scribed by Piero Mastrorilli; Francesco Muscio; Cosimo Francesco Nobile; Gian Paolo Suranna

Publisher: Elsevier Science
Year: 1999
Tongue: English
Weight: 74 KB
Volume: 148
Category: Article
ISSN: 1381-1169
DOI: 10.1016/s1381-1169(99)00039-4

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✦ Synopsis

The oxidation of alkyl and aryl phosphines, tryphenylphosphite and triphenylarsine was achieved using oxygen or air as Ž . the oxidant in the presence of excess 3-methylbutanal and catalytic amount Co acac . Tests carried out with a 2 Ž . heterogeneous analogue of Co acac revealed that the supported cobalt polymer acts as an active and reusable catalyst in 2 the oxidation of triphenylphosphine.

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