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Aerobic oxidation of cumene catalysed by 4-alkyloxycarbonyl-N-hydroxyphthalimide

✍ Scribed by Kasperczyk, Kornela; Orlińska, Beata; Zawadiak, Jan

Book ID
121821158
Publisher
SP Versita
Year
2014
Tongue
English
Weight
739 KB
Volume
12
Category
Article
ISSN
1895-1066

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Selective functionalisation of hydrocarb
Selective functionalisation of hydrocarbons by nitric acid and aerobic oxidation catalysed by N-hydroxyphthalimide and iodine under mild conditions
✍ Francesco Minisci; Francesco Recupero; Cristian Gambarotti; Carlo Punta; Roberto 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 145 KB

Alkylbenzenes are selectively functionalised to the corresponding acetates by nitric aerobic oxidation catalysed by N-hydroxyphthalimide and iodine. With cyclohexane the oxidation leads to a mixture of cyclohexyl acetate and trans-2-iodocyclohexyl acetate. The mechanism is discussed.