Aerobic Oxidation of Alcohols in Carbon Dioxide with Silica-Supported Ionic Liquids Doped with Perruthenate

✍ Scribed by Rosaria Ciriminna; Peter Hesemann; Joël J. E. Moreau; Massimo Carraro; Sandro Campestrini; Mario Pagliaro

• Publisher: John Wiley and Sons
• Year: 2006
• Tongue: English
• Weight: 182 KB
• Volume: 12
• Category: Article
• ISSN: 0947-6539
• DOI: 10.1002/chem.200501556

✦ Synopsis

Abstract

The replacement of toxic Cr^VI^ for O~2~ and of chlorinated solvents for supercritical carbon dioxide (or ionic liquids) in the oxidation of alcohols remains hindered by the low selectivity and activity of the current heterogeneous catalysts. Using an integrated approach that combines sol–gel entrapped perruthenate as aerobic catalyst, an encapsulated ionic liquid as solubility promoter, and scCO~2~ as the reaction solvent, we have developed a system capable of rapidly converting different alcohols into carbonyl compounds with complete selectivity, including substrates which are otherwise difficult to oxidise. The methodology is generally applicable and may easily be extended to other waste‐free, catalytic syntheses of fine chemicals.