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Advantage of Using tert -Hexyl Peroxypivalate as an Initiator for the Polymerization of Methyl Methacrylate

✍ Scribed by Nakamura, Tomoyuki; Busfield, W. Ken; Jenkins, Ian D.; Rizzardo, Ezio; Thang, San H.; Suyama, Shuji


Book ID
126808799
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
110 KB
Volume
29
Category
Article
ISSN
0024-9297

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In this study a controlled polymerization of styrene (S) and methyl methacrylate (MMA) with tetraphenylbisphosphine (TPhBP) as the initiator in bulk was carried out, using UV light as the energy source. The yield of polymerization was up to 15% for PS and up to 62% for PMMA. TPhBP is decomposed to f