Deviations from the additivity of energy contributions to substance sorption energies, determined on the basis of thermodynamic studies of GC behavior of homologous series of organic compounds fall into two categories: one for n-alkanes, the other for homologous series containing a functional group.
✦ LIBER ✦
Advantage of the universal equation over the linear equation for the calculation of retention parameters of homologous series in capillary chromatography
✍ Scribed by Svetlova, N. I. ;Samusenko, A. L. ;Golovnya, R. V.
- Publisher
- John Wiley and Sons
- Year
- 1986
- Tongue
- English
- Weight
- 390 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0935-6304
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## Abstract The Poisson–Boltzmann equation is widely used to describe the electrostatic potential of molecules in an ionic solution that is treated as a continuous dielectric medium. The linearized form of this equation, applicable to many biologic macromolecules, may be solved using the boundary e