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Advances in the Synthesis and Structural Description of 2H-Hexagonal Perovskite-Related Oxides

โœ Scribed by K. E. Stitzer; J. Darriet; H.-C. zur Loye


Publisher
John Wiley and Sons
Year
2003
Weight
4 KB
Volume
34
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

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The hexagonal perovskite-type oxides A x BO 3 (A โ€ซุโ€ฌ Ca, Sr, Ba; B โ€ซุโ€ฌ Co, Ni) consist of (BO 3 ) chains made up of face-sharing BO 6 octahedra and BO 6 trigonal prisms. On the basis of molecular orbital calculations for their structural building blocks we examined why the transition metal atoms in