Advances in Bioelectrochemistry Volume 1: Surface, Electron Transfer and Techniques

✍ Scribed by Frank N. Crespilho (editor)

• Publisher: Springer
• Year: 2022
• Tongue: English
• Leaves: 137
• Category: Library

✦ Synopsis

This book presents a collection of chapters on modern bioelectrochemistry, showing different aspects of electron transfer reactions in biological systems and techniques. The chapters cover computer simulation, biomolecules on surfaces, direct and mediated electron transfer, electron transfer kinetics, surface-confined biomolecules, field-effect transistor effects, supramolecular electrochemistry, in situ and operando techniques in bioelectrochemistry. They provide relevant bibliographic information for researchers and students interested in computer simulation involving biomolecules on surfaces, processes of direct and mediated electron transfer kinetics of cytochrome c, surface-confined biomolecules for application in bioelectronics, sensitive devices based on field-effect transistors, insights on supramolecular electrochemistry with recent trends and perspectives and technological innovation on instrumentation applied in operando techniques field.

✦ Table of Contents

Contents
Computer Simulation: Biomolecules on Surfaces
1 Introduction
2 Electron Transfer of Peptide SAMs Modified with Ferrocene
3 Two-Dimensional (2D) Systems
3.1 On Top Application Using Silicene
3.2 Nanogap Application with Graphene
3.3 Nanopore Application with Hybrid Graphene-BN Device
3.4 Surface Application with Graphene Functionalization
4 Conclusion
References
Direct and Mediated Electron Transfer in Enzyme Electrodes
1 Introduction
2 Redox Enzyme—Glucose Oxidase
3 Enzymatic Immobilization Processes
4 Direct Electron Transfer and Its Dependence on the Distance Between Enzyme and Electrode
5 Mediated Electron Transfer
6 Conclusion
References
A Case Study of Cytochrome c
1 Electron Transfer Reactions
2 Cytochrome c, a Brief Understanding
3 Cytochrome c Immobilization and Surface Modifiers to Direct Electrochemistry
4 Direct Electrochemistry of Cyt c at Nanomaterials-Modified Electrodes
5 Kinetic Modeling
6 Final Considerations
References
Surface-Confined Biomolecules for Application in Bioelectronics
1 Immobilization of Biomolecules
2 Surface-Confined Biomolecules—Chemical Functionalisation
3 Non-covalent Chemical Functionalisation
4 Covalent Chemical Functionalisation
5 Final Considerations
References
Sensitive Devices Based on Field-Effect Transistors
1 Introduction
2 Field-Effect Transistors Transducers
2.1 Historical Emergence of ISFET
2.2 Electrical Characteristics of ISFET
2.3 EGFETs and SEGFETs
2.4 OFETs
2.5 NanoFETs
2.6 New Trends: Tunable FETs
3 Final Remarks
References
Supramolecular Electrochemistry: Recent Trends and Perspectives
1 General Overview
2 Versatile Building Blocks Used for Supramolecular Self-Assembly
2.1 Metallic Nanoparticles
2.2 Semiconductor Oxides
2.3 Carbon-Based Materials
2.4 Coordination Compounds
2.5 Others Classes of (Nano)materials
3 Methods of Building Blocks Supramolecular Assembly onto Electrode Surfaces
3.1 Self-Assembled Monolayes (SAMs)
3.2 LbL Self-Assembled
3.3 Electrochemical Deposition
4 Applications of Supramolecular Structures
5 Conclusions
References
In Situ and Operando Techniques in Bioelectrochemistry
1 Introduction
2 Restraints Involved in Combining Bioelectrochemistry with Analytical Techniques
3 In Situ and Operando Spectroscopies in Bioelectrochemistry
3.1 Operando and In Situ Electronic Spectroscopies in Biolectrochemistry
3.2 Vibrational Spectroelectrochemistry in Bioelectrochemistry
3.3 Magnetic Spectroscopies Applied in Bioelectrochemistry
4 Non-spectroscopy In Situ and Operando Techniques in Bioelectrochemistry
5 Overview
References