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Advanced Organic Chemistry || Additions to the Olefinic C=C Double Bond

✍ Scribed by Bruckner, Reinhard

Book ID
120419184
Publisher
Elsevier
Year
2002
Tongue
English
Weight
586 KB
Edition
1
Category
Article
ISBN
0121381102

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✦ Synopsis

A best-selling mechanistic organic chemistry text in Germany, this text's translation into English fills a long-existing need for a modern, thorough and accessible treatment of reaction mechanisms for students of organic chemistry at the advanced undergraduate and graduate level. Knowledge of reaction mechanisms is essential to all applied areas of organic chemistry; this text fulfills that need by presenting the right material at the right level.

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## Abstract Tricyclic olefinic alcohols containing an unsymmetrically alkyl‐substituted C, C‐double bond were cyclized intramolecularly to their corresponding ethers under basic conditions: **9 β†’ 12**, **10 β†’ 17 + 18**, and **11 β†’ 12** __(Scheme 3, Table 1)__. The reactivity is mainly due to reliev

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## Abstract The tricyclic olefinic primary amine **1** readily cyclizes to the tetracyclic secondary amine **2** at approximately 200Β° in protic as well as aprotic solvents although the C, C‐double bond is not activated by electron‐attracting groups. This unusual intramolecular addition is the cons