A sensltlve adsorptive voltammetnc procedure for the determmatlon of trace copper, based on the adsorption charactenstlcs of the copped111 complex wth Beryllon III at a hangmg mercury drop electrode (HMDE), IS described The results show that the best base solution consists of 0 02 mol I-' acetIc aci
Adsorption voltammetry of beryllium in the presence of 4-[(4-diethylamino-2-hydroxyphenyl) azo]-5-hydroxy- naphthalene-2,7-disulphonic acid (Beryllon III)
โ Scribed by Changlin Sun; Jianyan Wang; Wei Hun; Tianao Xie; Wenrui Jin
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 396 KB
- Volume
- 259
- Category
- Article
- ISSN
- 0003-2670
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โฆ Synopsis
The adsorptive voltammetrlc behavlour of Be(U) at a hangmg mercury drop electrode (HMDE) m the presence of Beryllon III was mvestlgated m NH,-NH&l (pH 9 7) solution The results show that the Be(H) complex wrth Beryllon III can be adsorbed on the surface of the HMDE, yleldmg one peak at -0 78 V (vs SCE), correspondmg to the reduction of Beryllon III m the complex at the electrode The lurut of detectlon IS as low as 5 X lo-" mol 1-l The lmear range 1s 1 X 10e9-8 X lo-* mol 1-l
๐ SIMILAR VOLUMES
The behavior of Ti (N) complex with Beryllon 111, Ti ( W ) A, at a mercurv electrode has been investigated in acetate buffer (HOAc/NaOAc). The adsorption phenomena were observed by linear-sweep voltammetry. The mechanism of the electrode reaction was found to be the irreversible reduction of Beryllo