In this work, polyacrylonitrile hollow fiber was oxidized, carbonized, and activated by carbon dioxide into activated hollow carbon fiber. The effects of the activation temperature on the characteristics of the resulting activated hollow carbon fiber, including the mechanical properties, the surface
Adsorption properties of polyacrylonitrile-based activated carbon hollow fiber
β Scribed by Junfen Sun; Guangxiang Wu; Qingrui Wang
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 121 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
Abstract
In this work, polyacrylonitrile (PAN) hollow fibers are pretreated with ammonium dibasic phosphate and then further oxidized in air, carbonized in nitrogen, and activated with carbon dioxide. The adsorption properties of the resultant activated carbon hollow fibers (ACHF) prepared in different conditions were studied. The results show that the adsorption properties of ACHF change regularly with preparing conditions of ACHF. The different adsorption ratios to three adsorbates reflect the number of micropores and mesopores in PANβbased ACHF. Pretreatment with phosphate can increase the number of mesopores. Proper oxidation temperature and time can increase the number of micropores and mesopores. When carbonization temperature is more than 900Β°C and carbonization time ranges from 50 to 90 min, the number of micropores and mesopores, especially mesopores, greatly increases. Compared with other treatments, activation treatment greatly increases the number of micropores and mesopores, and the dominant pore sizes of mesopores in PANβbased ACHF are from 2 to 10 nm. Β© 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 602β607, 2004
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## Abstract Polyacrylonitrile (PAN) hollow fibers were pretreated with ammonium dibasic phosphate, then further oxidized in air, carbonized in nitrogen, and activated with carbon dioxide. The effects of activation time of a precursor fiber on the microstructure, specific surface area, poreβsize dis
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