Adsorption Properties of Hydrogen and Carbon Dioxide in Prussian Blue Analogues M 3 [Co(CN) 6 ] 2 , M = Co, Zn
โ Scribed by Natesakhawat, Sittichai; Culp, Jeffrey T.; Matranga, Christopher; Bockrath, Bradley
- Book ID
- 126884105
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 202 KB
- Volume
- 111
- Category
- Article
- ISSN
- 1932-7447
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Tetrapropylammonium and -phosphonium ions, nPr 4 E ุ , react readily with the polymeric super-Prussian blue derivatives [(Me 3 Sn) 3 M(CN) 6 ] (M โซุโฌ Co, Ir), which are built up of in5nite [ +M+CN+Sn+NC] + chains, a4ording the dimorphic supramolecular assembly [(nPr 4 E)(Me 3 Sn) 2 M(CN) 6 ' 2H 2 O]