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Adsorption Properties of Hydrogen and Carbon Dioxide in Prussian Blue Analogues M 3 [Co(CN) 6 ] 2 , M = Co, Zn

โœ Scribed by Natesakhawat, Sittichai; Culp, Jeffrey T.; Matranga, Christopher; Bockrath, Bradley


Book ID
126884105
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
202 KB
Volume
111
Category
Article
ISSN
1932-7447

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Tetrapropylammonium and -phosphonium ions, nPr 4 E ุ‰ , react readily with the polymeric super-Prussian blue derivatives [(Me 3 Sn) 3 M(CN) 6 ] (M โ€ซุโ€ฌ Co, Ir), which are built up of in5nite [ +M+CN+Sn+NC] + chains, a4ording the dimorphic supramolecular assembly [(nPr 4 E)(Me 3 Sn) 2 M(CN) 6 ' 2H 2 O]