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Adsorption of the N,N'-dimethyl-4,4′-bipyridinium cation (MV2+) and of the [Rh (bipy)3]3+ complex on Pt, Au and Pt + Au electrodes

✍ Scribed by O. Enea

Book ID: 103064704
Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 421 KB
Volume: 30
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(85)80052-9

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✦ Synopsis

Absbsct-Voltannnetric mcasnrements with "model" electrodes (Pt, Au, pt + Au, _ _ . ) were carried out at different concentrations of MV'* and [Rh(bipy)J3+ cations in order to establish their adsorption onto the surface and to compare theii behaviour in interfacial electron transfer reactions at various pH values.

The role of MV3+ as an electron relay in artiiieiql photosynthetic devices is examined on the basis of its preferential adsorption onto noble metal particles or deposits.

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