𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Adsorption of T1(I) on mercury in thiocyanate media

✍ Scribed by S. González; P. Carro; A. Arévalo

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
347 KB
Volume
30
Category
Article
ISSN
0013-4686

No coin nor oath required. For personal study only.

✦ Synopsis

The adsorption of Tl(I) on the Hg electrode in thiocyanate-trifluoracetate media is studied by double-step chronocoulometry. The adsorption amount increases with the concentration of thioc anate and decreases when the potential becomes anodic. The results indicate that the species adsorbed is x SCN, and that no bridge mechanism takes place, as would be expected in adsorption induced by SCN-.

📜 SIMILAR VOLUMES

Spectrophotometric determination of chlo
Spectrophotometric determination of chloride in non-polar media by the mercury(II) thiocyanate reaction
✍ B. Vekić; D. Ražem 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 372 KB

A simple, rapid and accurate method for the spectrophotometric determination of chloride in non-polar media is described. The method is based on the well-known reaction of mercury(I1) thiocyanate with chloride to release thiocyanate, which then reacts with iron(II1). The optimum concentrations of re